Pesticides and herbicides are critical to ensuring food security worldwide, but these substances can present a safety risk to people who unwittingly ingest them.
Pesticides and herbicides are critical to ensuring food security worldwide, but these substances can present a safety risk to people who unwittingly ingest them. Protecting human health, therefore, demands sensitive analytical methods to identify even trace levels of potentially harmful substances. Now, researchers reporting in ACS’ Nano Letters have developed a high-tech imaging method to detect pesticide contamination at low levels, and its application on fruits reveals that current food safety practices may be insufficient.
The analytical method called surface-enhanced Raman spectroscopy (SERS) is gaining popularity as a nondestructive method for detecting chemicals from modern farming on produce. With SERS, metal nanoparticles or nanosheets are used to amplify the signals created by molecules when they are exposed to a Raman laser beam. The patterns created by the metal-enhanced scattered light serve as molecular signatures and can be used to identify small amounts of specific compounds. Looking to improve SERS sensitivity for pesticide detection, Dongdong Ye, Ke Zheng, Shaobo Han and colleagues designed a metal-coated membrane they could lay atop farm-grown produce. They also wanted to develop the material to be versatile enough to accommodate an array of other applications.
The researchers started with a cellulose hydrogel film, which they stretched to form aligned nanoscale wrinkles along its surface. They then immersed the film in a solution of silver nitrate to coat the grooves with SERS-enhancing silver nanoparticles. The resulting membrane was highly flexible and practically transparent in visible light, essential features for SERS signal detection.
Read more at American Chemical Society
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