Efficient organic solar cells with very low driving force

It was believed that efficient operation of organic solar cells requires a large driving force, which limits the efficiency of organic solar cells. Now, a large group of researchers led by Feng Gao, lecturer at IFM at LiU, He Yan at the Hong Kong University of Science and Technology, and Kenan Gundogdu at the North Carolina State University have developed efficient organic solar cells with very low driving force.

This implies that the intrinsic limitations of organic solar cells are no greater than those of other photovoltaic technologies, bringing them a step closer to commercialisation.

When photons emitted by the sun are absorbed by organic semiconductors, strongly bound excitons (rather than free carriers) are generated. The driving force is, to put it simply, a measure of the energy that is used to split the excitons into free carriers. The driving force results in the loss of the photovoltage, a key parameter for the solar cell. The lower the driving force, the higher the photovoltage.

Traditionally, efficient organic solar cells are usually composed of semiconducting polymers and carbon balls known as ‘fullerene’. In that case, a large driving force over 0.3 eV is usually needed for efficient charge generation. In the present work, the researchers have replaced fullerene with a semiconducting small molecule, and found that that a low driving force is needed for efficient operation of the devices. In addition, organic solar cells based on polymer: small molecule combinations are more stable, as shown in another work also led by Feng Gao and his collaborators in Beijing, published in Advanced Materials.

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Image Credits: Konarka