Forget mousetraps -- today's scientists will get the cheese if they manage to build a better battery.
An international team led by Texas A&M University chemist Sarbajit Banerjee is one step closer, thanks to new research published today (June 28) in the journal Nature Communications that has the potential to create more efficient batteries by shedding light on the cause of one of their biggest problems -- a "traffic jam" of ions that slows down their charging and discharging process.
All batteries have three main components: two electrodes and an intervening electrolyte. Lithium ion batteries work under the so-called rocking-chair model. Imagine discharging and charging a battery as similar to the back-and-forth motion of a rocking chair. As the chair rocks one way, using its stored energy, lithium ions flow out of one electrode through the electrolyte and into the other electrode. Then as the chair rocks the other way, charging the battery after a day's use, the reverse happens, emptying the second electrode of lithium ions.
Forget mousetraps -- today's scientists will get the cheese if they manage to build a better battery.
An international team led by Texas A&M University chemist Sarbajit Banerjee is one step closer, thanks to new research published today (June 28) in the journal Nature Communications that has the potential to create more efficient batteries by shedding light on the cause of one of their biggest problems -- a "traffic jam" of ions that slows down their charging and discharging process.
All batteries have three main components: two electrodes and an intervening electrolyte. Lithium ion batteries work under the so-called rocking-chair model. Imagine discharging and charging a battery as similar to the back-and-forth motion of a rocking chair. As the chair rocks one way, using its stored energy, lithium ions flow out of one electrode through the electrolyte and into the other electrode. Then as the chair rocks the other way, charging the battery after a day's use, the reverse happens, emptying the second electrode of lithium ions.
"Fundamentally, when you have a battery, every time you use it, it starts to die a little bit," Banerjee said. "The more you use it, the more it dies. Eventually, it becomes unusable. Theoretically speaking, you expect a certain performance from a battery, and you rarely ever get there. People have been at a loss to understand all the factors that contribute to this lack of full capacity. This study points us in that direction."
Using one of the world's most powerful soft X-ray microscopes -- the Scanning Transmission X-ray Microscope (STXM) -- at the Canadian Light Source (CLS) in tandem with decades of combined experience in materials science, Banerjee and collaborators from the Lawrence Berkeley National Laboratory, Binghamton University and the National Institute of Standards and Technology (NIST) were able to image a traffic jam of lithium ions chemically driven through the nanowire-based channels of a simulated battery.
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Image credit: NIST.gov
