The global climate crisis, driven by the depletion of fossil fuels and rising atmospheric CO2 levels, has intensified the need for sustainable energy solutions.
The global climate crisis, driven by the depletion of fossil fuels and rising atmospheric CO2 levels, has intensified the need for sustainable energy solutions. Among these, the electrochemical CO2 reduction reaction (CO2RR), particularly when integrated with renewable energy sources, has emerged as a promising approach. This process not only mitigates CO2 emissions but also addresses energy storage challenges by converting CO2 into high-value, carbon-neutral fuels. One of the standout products of CO2RR is formic acid (HCOOH), valued for its versatility in industries such as tanning, textiles, and pharmaceuticals, as well as its role as a high-energy-density liquid hydrogen storage medium.
"Formic acid is an indispensable chemical in various industries, and its potential as a hydrogen carrier makes it a critical component for a sustainable energy future," said Xue Jia, an assistant professor at Tohoku University's Advanced Institute for Materials Research (WPI-AIMR). Recent techno-economic analyses have also highlighted the practicality and economic feasibility of synthesizing formic acid through CO2RR, emphasizing its adaptability for future industrial applications.
To advance the development of efficient CO2RR catalysts, Jia and her colleagues conducted a comprehensive study, analyzing over 2,300 experimental reports from the past decade. Their findings underscored the superior activity and selectivity of tin-based catalysts, such as Sn−N4−C single-atom catalysts (SAC) and polyatomic Sn, for HCOOH production. These catalysts consistently outperformed others, including metal-nitrogen-carbon (M−N−C) catalysts and various metals, in terms of formic acid Faradaic efficiency (FE).
Read more at Tohoku University
